From memory, Frankfurt-Cologne is pretty good, travelling through the Taunus hills with good views (and you can feel the gradient changes as it's an undulating line).
Paris-Marseille also good once you've got off the northern plain and are in Burgundy and beyond (also steeply graded north of Lyon).
I've spotted Mont Blanc from a TGV south of Lyon on this line, and there are several crossings of the Rhone, plus Mont Ventoux rising east of Avignon.
Other LGV's out of Paris are all very flat until you reach some hills or the coast.
Naples-Rome was interesting, and the southern link to Salerno passes "round the back" of Vesuvius.
Bologna-Florence (78km) is 93% in tunnel, but it does emerge briefly in the gaps between the 9 tunnel sections.
Florence-Rome is good too in the hilly bits.
Turin-Milan-Bologna is pretty much flat, but you do see Milan's skyscrapers emerging from the haze.
That's also true of the northern approach to Madrid (from Valladolid/Segovia) over the vast Spanish meseta.
The Gotthard Base tunnel is 230km/h but there is no view for 57km (longer than the Channel Tunnel, but as the speed is faster, transit time is similar at 20 minutes).
The Lötschberg Base tunnel is similar at 37km.
Luckily you can still do both of the old winding Swiss routes with shorter tunnels and superb views, if you have the time.
The other base Alpine tunnels under construction (Brenner, Semmering, Koralm, Mont d'Ambin) will be similarly tedious.
Erfurt-Nuremberg should be good, through the Thuringian/Bavarian hills.
Zamora-Ourense in Spain ought to be good too, though it bypasses a superb mountain classic line.
I've done Madrid-Alacant and the southern half of that is through very rough, volcanic country.
Your 220km/h includes quite a few German/Austrian upgraded fast lines (ABS rather than NBS).
Berlin-Hanover/Hamburg/Leipzig are all tediously flat.
I found Linz-Vienna interesting (views of the Danube), and when the Basel-Karlsruhe line's upgrade has finished I suspect it will be quite scenic.
The "CMK" in Poland (the central part of Warsaw-Katowice/Krakow routes) is 200km/h but due to go up to 250km/h - also very flat.