As I understand it, the reason we hear pylons humming is because they're AC, the tube is DC so shouldn't produce any noise (regardless of pitch!). It's more likely that cats are just sensitive to electromagnetic fields (which are generated by DC) but unfortunately google searching brings up a lot of conspiracy theorist type results (and this hilarious image)
There's a lot we don't know about cats level of hearing and sensitivity to electrical flows, DC may produce sound that we are completely unaware of, I'm more inclined to think they can hear electric flows through the metal producing a resonance that only they can hear.
I used to drive vintage trams and we were taught to think of electricity as water, how it flows, resistance and amperes.
So think of a narrow pipe of water flowing the smaller it is ( higher resistance), flow rate (amperes) headtank of 600 gallons per section (voltage)
That's why I think the cats hear it more than we do.
There's much more of the physical world yet to be discovered yet we don't have the technology to discover them.
Like the tin foil cat