The standard method of measuring reliability of all train fleets is for each four week period the average mileage between technical faults that cause delays to passengers. It's known as Mp701D. No idea what that stands for.
Faults that don't incur delays to passengers aren't included as a measure for any fleet.
In the latest issue of Modern Railways, Roger Ford's league table of new units has figures for fifteen classes, ranging from 522 Mp701D for class 777 to 20,789 for class 710/1. Aventras occupy five of the top six places (classes 710/1, 720, 710/2 and 720/6, 730) with class 345 in ninth.
But as Captain Deltic observes, this is just a snapshot - for example over the past year class 710/1s monthly figures have fluctuated between 7,000 and 29,000, with an average of 14,000. And of course for the 701s, a second failure would instantly halve the Mp701D figure!
The 701s have now run on 62 days, the first four of which had one round trip and the others had two, making a total of 119 (excluding the one that was cancelled last month) Waterloo to Windsor is a 52 mile round trip, so that's 6,188 Mp701D (7,116 if you include ECS workings to enter and leave passenger service), which would put them in sixth place, between Class 195/0 (8,692 Mp701D) and Class 730 (5,947).
But its barely 2,000 if you take the figures for March alone (39 round trips), putting it 13th, just above class 769