Depends on driver (see above) and conditions. I've seen 0 to 60mph in 27 seconds and 0 to 100mph in under 70 seconds on a 755/3 (electric mode) given the full beans departing Stowmarket non-stop towards Ipswich - which makes it by far - the fastest accelerating train in the UK. And measured with RAcelogic Vbox professional GPS timing gear too - not a Garmin!
I had a 755/4 given full power start from Colchester in torrential rain in electric mode. The traction electronics were working overtime to prevent wheelslip - which even occurred at 80mph - and despite that - it still beat a Class 360 timing recorded in dry conditions! Those Stadlers are phenomenal!
Rail Express is playing catchup - we cannot get the info to them fast enough!
Officially the 755/3's are fastest - 0 to 60mph in 27 seconds, followed by 755/4 (31 seconds from memory) and possibly 331 3-car units after that.
345's were 36 seconds (0 to 80mph in 1 minute!) , and the latest Class 720 seems to be achieving 0 to 60mph in 39 seconds - which is on a par with a Class 745/1.
Class 710's are not so easy to record reliable data on. LO drivers seem to start off in a low power setting for 5 to 10 seconds before giving them full beans - and there is nowhere to record a full 0 to 60mph on the LO network.
The 710's are a lot faster than the 172's for sure, but from 0 to 45mph..the 710's are only slightly faster than a 378.
Out of interest, which is quicker between a 332 & a 397? Old CAF vs New CAF.